Online Highways Home > Tennessee > Maynardville City Map with Features Union County The county seat of Union County, Tennessee, is Maynardville. The county population on July 1, 1999, was 16,584, an increase of 2,890 over the 1990 census. For information on county government, contact the National Association of Counties Web site. Additional information is available at these pages: Tennessee Counties Tennessee Cities and Towns Read reviews and find hotels in Maynardville. Location: Maynardville Tennessee See more Tennessee Counties. Other upcoming events include:

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